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Session: Session 19: Large-scale ORC units II
Session starts: Wednesday 14 October, 14:00
Presentation starts: 14:20
Room: 1B Europe

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Tobias Erhart (University of Applied Sciences Stuttgart)
Jürgen Gölz (BIOP GmbH)
Ursula Eicker (University of Applied Sciences Stuttgart)
Martijn van den Broek (Ghent University)

Abstract:
The results in this work show the influence of long-term operation on the decomposition of working fluids in eight different power plants (both heat-led and electricity-led) in a range of 900 kWel to 2 MWel. All case study plants are using Octamethyltrisiloxane (MDM) as a working fluid. The case study plants are between six to 12 years old. On one system detailed analyses, including the fluid distribution throughout the cycle, have been conducted. All fluid samples have been analysed via Head Space Gas Chromatography Mass Spectrometry (HS-GC-MS). Besides the siloxane composition, the influence of contaminants such as mineral oil based lubricants (and its components) has been examined. In most cases the original main working fluid has degraded to fractions of siloxanes with a lower boiling point (low-boilers) and fractions with a higher boiling point (high-boilers). As a consequence of the analyses, a new fluid management system has been designed and tested in one case study plant (case study number 8). The measures include fluid separation, cleansing and recycling. Pre-post comparisons of fluid samples have proved the effectiveness of the methods. The results show that the recovery of used working fluid offers an alternative to the purchase of fresh fluid, since operating costs can be significantly reduced. For large facilities the prices for new fluid range from 15€ per litre (in 2006) to 22€ per litre (in 2013), which is a large reinvestment, especially in the light of filling volumes of 4000 litres to 7000 litres per cycle. With the above mentioned method a price of 8€ per litre of recovered MDM can be achieved.